Analysis of organic materials

Characterization of organic materials

CIRAM supports carries out the analysis of organic materials present in works of art, archaeological artifacts, and industrial materials: varnishes, residues, waxes, binders.

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A scientist taking a sample from a wooden statue

Characterizing organic materials:
essential expertise for art, archaeology and industry

The analysis of organic materials aims to identify, by chemical or isotopic means, substances of natural or synthetic origin present in a heritage object or an industrial material. This characterization technique primarily targets:

  • Visit organic residues (fats, oils, waxes, proteins);
  • Visit binders and varnishes used in pictorial layers or finishes;
  • Visit bio-based compounds entering the formulation of industrial polymers.

In the art market, it can be used to assess the historical and technological coherence of an object, or to authenticate a work of art. In archaeology, it provides functional information on past uses (containers, rituals, techniques). In an industrial context, it provides guarantees on the composition, origin or conformity of a material.

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Unrolling a papyrus scroll to verify the authenticity of the artwork

Means used to characterize organic materials

CIRAM supports uses several complementary methods, selected according to the nature of the samples and the objectives of the study:

  • The Raman spectroscopy, particularly suited for the identification of polymers, resins, waxes, or varnishes, directly on the object or from a micro-sample.
  • The FT-IR spectroscopy (Fourier Transform Infrared) allows for rapid identification of functional groups present in organic compounds. Effective for complex mixtures and degraded materials.
  • The Gas chromatography-mass spectrometry (GC-MS) analyzes organic mixtures in depth (natural resins, oils, binders, waxes) and allows for comparison with reference databases.
  • Elemental analysis coupled with isotope ratio mass spectrometry (EA-IRMS) provides isotopic signatures for carbon (¹³C/¹²C) and nitrogen (¹⁵N/¹⁴N). This method is used to determine the biological origin of a material or to assess the biobased content according to ISO 16620-2.

These methods can be used alone or in combination to obtain robust results that can be exploited in a heritage or industrial context.

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Residues, binders, varnishes :
materials with a high index value

01 - Organic residues on archaeological objects

In the field of archaeologydating, organic residues absorbed or embedded on ceramics, tools, or ritual objects offer valuable information about past uses:

  • Nature of products contained (oils, resins, fats, etc.),
  • Processing and preservation methods,
  • Exploited plant or animal sources.

Using GC-MS or FTIRanalysis, CIRAM helps archaeologists to reconstruct the food, medicinal and craft practices of ancient civilizations.

02 - Binders and varnishes in works of art

In the art marketthe identification of binders or varnishes (natural resins, drying oils, waxes, animal glues) makes it possible to authenticate works of artand date their creation. Certain chemical signatures are characteristic of specific periods, geographical areas or workshops.

From Raman or FTIR spectra allow these components to be identified, and their study compared to historical reference databases refines the analysis.

03 - Industrial waxes and bio-based materials

To industryparticularly in the packagingtextile and polymer sectors, elemental and isotopic analysis (EA-IRMS) can be used to :

  • Check the natural or synthetic origin of materials,
  • Determine the biobased content (in accordance with ISO 16620-2),
  • Check product compliance with regulatory or environmental requirements.

CIRAM, expert in organic materials analysis

When you call on CIRAM for your organic analyses, you benefit from recognized expertise, scientific rigor and cutting-edge analytical technologies.
CIRAM relies on :

  • From highly sensitive and complementary instruments (Raman, IRTF, GC-MS, EA-IRMS),
  • Reference databases for reliable interpretation of spectra,
  • One multidisciplinary team capable of associating different techniques – spectrometry, microanalysis, metallography, chromatography, X-ray radiography – to offer a rigorous and contextualized interpretation of the results.
  • From validated protocols to ensure the reproducibility and traceability of results.

supports museum institutions, archaeologists, auction houses, art restorers or manufacturers in their projects in France and abroad.

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Are you asking yourself these questions?

Is it possible to analyze a varnish on an old painting?

Yes, FTIR or GC-MS analysis can identify the exact nature of the varnish, whether natural (dammar, mastic...) or synthetic.

Can a wax be authenticated?

Yes, chromatographic analysis identifies its composition (bee, carnauba, synthetic...) and can reveal its origin or use.

Does this technique damage the object being analyzed?

No. The methods are non-destructive or require only a micro-sample (<1 mg) depending on the case.

Is it possible to authenticate a work of art using organic analysis?

Yes, binders and varnishes are reliable indicators of any anachronisms or chemical signatures specific to a particular period.

How much does an analysis of organic materials cost?

The cost depends on the number of techniques used, the type of object, the nature of the sample and the degree of interpretation required. Contact us for a personalized quote.

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